Solar energy in the context of energy use, energy transportation, and energy storage David J C MacKay FRS; Article submitted to Royal Society; 2013?
- Taking the United Kingdom as a case study, this paper describes current energy use and a range of sustainable energy options for the future, including solar power and other renewables. I focus on the the area involved in collecting, converting, and delivering sustainable energy, looking in particular detail at the potential role of solar power.
- Last year, 5.7% of Germany’s electricity generation and 2.5% of primary energy consumption came from solar panels.
Which Is Cheaper -- Rooftop Solar Or Utility-Scale Solar? James Conca; Forbes; 30 Jul 2015
- 1 technology
- 1.1 hybrid
- 1.2 rectennas
- 1.3 Chemical
- 1.4 PV
- 1.5 Concentrating
- 1.6 solar wind energy
hybrid solar pv / thermal Ellen D Williams, ARPA-E; MIT solar day (powerpoint presentation); 10 Sep 2015
- A new kind of nanoscale rectenna (half antenna and half rectifier) can convert solar and infrared into electricity, plus be tuned to nearly any other frequency as a detector.
- Right now efficiency is only one percent, but professor Baratunde Cola and colleagues at the Georgia Institute of Technology (Georgia Tech, Atlanta) convincingly argue that they can achieve 40 percent broad spectrum efficiency (double that of silicon and more even than multi-junction gallium arsenide) at a one-tenth of the cost of conventional solar cells (and with an upper limit of 90 percent efficiency for single wavelength conversion).
solar energy splitting CO2 and H2O to CO and H2 syngas
New Solar Device Removes Carbon Dioxide From the Atmosphere Emily J. Gertz; takepart; 28 Jul 2016
- a team of scientists announced in the journal Science that they have created a device that absorbs carbon dioxide from the atmosphere and uses sunlight to break it into a mix of carbon monoxide and hydrogen called synthesis gas or “syngas,” that can be used directly or turned into diesel or other liquid fuels,
- the device’s chemical catalyst—necessary for breaking down the CO2—is not a costly metal such as platinum, palladium, or silver but a “nanoflake tungsten diselenide.”
Nanostructured transition metal dichalcogenide electrocatalysts for CO2 reduction in ionic liquid Mohammad Asadi, Kibum Kim, Cong Liu, Aditya Venkata Addepalli, Pedram Abbasi, Poya Yasaei, Patrick Phillips, Amirhossein Behranginia, José M. Cerrato, Richard Haasch, Peter Zapol, Bijandra Kumar, Robert F. Klie, Jeremiah Abiade, Larry A. Curtiss, Amin Salehi-Khojin; Science; 29 Jul 2016
- Most artificial photosynthesis approaches focus on making hydrogen. Modifying CO2, as plants and microbes do, is more chemically complex. Asadi et al. report that fashioning WSe2 and related electrochemical catalysts into nanometer-scale flakes greatly improves their activity for the reduction of CO2 to CO. An ionic liquid reaction medium further enhances efficiency. An artificial leaf with WSe2 reduced CO2 on one side while a cobalt catalyst oxidized water on the other side.
- Conversion of carbon dioxide (CO2) into fuels is an attractive solution to many energy and environmental challenges. However, the chemical inertness of CO2 renders many electrochemical and photochemical conversion processes inefficient. We report a transition metal dichalcogenide nanoarchitecture for catalytic electrochemical CO2 conversion to carbon monoxide (CO) in an ionic liquid. We found that tungsten diselenide nanoflakes show a current density of 18.95 milliamperes per square centimeter, CO faradaic efficiency of 24%, and CO formation turnover frequency of 0.28 per second at a low overpotential of 54 millivolts. We also applied this catalyst in a light-harvesting artificial leaf platform that concurrently oxidized water in the absence of any external potential.
Max-Planck-Institute (MPI) for Terrestrial Microbiology / Lawrence Berkeley National Lab(?) enzyme
Engineering a more efficient system for harnessing carbon dioxide Science Daily; 17 Nov 2016
- Source: Lawrence Berkeley National Laboratory
- Scientists have reverse engineered a biosynthetic pathway for more effective carbon fixation that is based on a new CO2-fixing enzyme that is nearly 20 times faster than the most prevalent enzyme in nature responsible for capturing CO2 in plants by using sunlight as energy.
- Despite the vast diversity of organisms on the planet that express enzymes for the conversion of carbon dioxide into such organic compounds as sugars -- as plants do through photosynthesis -- the efforts to harness these capabilities to transform CO2 into high-value products such as biofuel and renewable chemicals have met with limited success. While increasing concentration of CO2 in the atmosphere poses a challenge, researchers also see it as an opportunity.
- Now a team from the Max-Planck-Institute (MPI) for Terrestrial Microbiology in Marburg, Germany, by tapping the DNA synthesis expertise of the U.S. Department of Energy Joint Genome Institute (DOE JGI), has reverse engineered a biosynthetic pathway for more effective carbon fixation. This novel pathway is based on a new CO2-fixing enzyme that is nearly 20 times faster than the most prevalent enzyme in nature responsible for capturing CO2 in plants by using sunlight as energy. The study was published in the November 18, 2016 issue of Science.
Tobias Erb on Designing a More Efficient System for Harnessing Carbon Dioxide DOE Joint Genome Institute; YouTube; 17 Nov 2016
Ricardo Grau-Crespo / University of Reading
Reading scientists design material that could turn carbon dioxide into fuel Nathan Hyde; getReading; 26 Nov 2016
- University of Reading scientists have designed materials which could be used to combat global warming.
- The hypothetical materials have the precise molecular structure needed to absorb harmful carbon dioxide emissions and convert them into useful chemicals such as methanol by using sunlight.
- The pioneering research, conducted by a team in Reading's Chemistry Department, could pave the way for other researchers to create porous photocatalyst materials.
- Theoretically, the materials could also be used to absorb solar energy and split water into oxygen and hydrogen elements. These could then be recombined in fuel cells to produce energy and water.
- Dr Ricardo Grau-Crespo, who led the research, said: “This might look like science fiction, but the possibility of synthesizing these versatile materials is very real, and could be achieved within a year based on our designs.
MATERIAL INSPIRED BY NATURE COULD TURN WATER INTO FUEL ; University of Reading; 20 Oct 2016
- Scientists have theoretically designed a new material that could help supply the world with clean energy by turning water into fuel, using just the power of the sun.
- Chemists at the University of Reading say a new catalyst, which mimics the way plants absorb energy from the sun, could make the energy-sapping job of splitting water into hydrogen and oxygen relatively easy.
- As well as potentially being able to produce hydrogen for fuel cells, the complex new material could also be used to turn carbon dioxide from the air into a carbon-based fuel, such as methanol.
- Dr Ricardo Grau-Crespo, from the Chemistry Department of the University of Reading, led the team that made the discovery.
- "Finding a material that can help create readily available fuels is one of the holy grails of science," he said.
- "While we still have a long way to go, our new findings could be a significant step forward in the search for cheaper, environmentally-friendly fuels to power the future."
- Splitting water into hydrogen and oxygen is an energy-intensive process, which currently requires much more energy in from electricity than comes out in usable fuel.
- To make the process more efficient, scientists use a photocatalyst - a material that absorbs light from the sun and uses it to excite electrons to higher energy levels. These excited electrons, and the empty spaces they leave behind, are then capable of driving forward the two half-reactions required to split water into oxygen and hydrogen.
- Unfortunately, finding a good photocatalyst is tricky as its properties have to be very precise to allow the reaction to take place. One of the best photocatalyst material available, titanium oxide, is too inefficient to produce more than a tiny amount of hydrogen, as it can only absorb energy from ultraviolet light.
- The Reading-led team used supercomputer simulations to look at many different candidates as potential photocatalysts for fuel production reactions.
- In new research, published in the Royal Society of Chemistry's Journal of Materials Chemistry A, they found that some metal-organic frameworks, which combine metal atoms and organic molecules, exhibit the ideal electronic structure required to catalyse these reactions.
- Dr Grau-Crespo said: "Our research is inspired by nature, as porphyrin is related to chlorophylls, the green pigments which allow plants to convert sunlight into chemical energy.
- "The challenge now is to incorporate these wonderful natural catalysts into materials capable of doing the specific chemical job we need. If we can do this, it could lead to highly-efficient conversion of solar energy to chemical energy - providing a clean, storable and transferrable source of energy."
- This new research was a collaboration between the University of Reading, UK, and the University Pablo de Olavide in Seville, Spain, and was funded by an International Exchange grant from the Royal Society.
Electronic structure of porphyrin-based metal–organic frameworks and their suitability for solar fuel production photocatalysis Said Hamad, Norge C. Hernandez, Alex Aziz, A. Rabdel Ruiz-Salvador, Sofia Caleroa, Ricardo Grau-Crespo; Journal of Materials Chemistry A; 14 Oct 2015 (also at )
- The development of cheap, efficient techniques to carry out the photocatalytic splitting of water would permit the generation of a clean fuel (hydrogen) at low negative environmental impact.
- Of similar interest is the photocatalytic reduction of CO2, which would allow the synthetic production of carbon-containing fuels (e.g. methanol) and simultaneously contribute to recycle CO2 from the environment. It is clear that the development of efficient technologies to carry out these energetically up-hill reactions using solar energy would be greatly beneficial, and therefore, many research efforts are being devoted to it, in particular to the search for adequate photocatalysts. This research was initially focused on traditional inorganic semiconductors, such as TiO2 and CdS, but it has now extended to a wider class of materials, including nanostructures such as fullerenes, nanotubes and graphene-like 2D solids. On the other hand, water splitting and CO2 reduction are at the core of natural photosynthetic reactions, so the study of the related natural processes can help finding artificial routes for these reactions. Bioinspired molecular photocatalysts have been largely studied in recent years.
- Besides Mn-complexes that are close to natural photosynthesis reactions, porphyrins have also been identified as active molecular centres for artificial photosynthesis. One drawback of molecular systems from a practical point of view is their recyclability, as the separation of the catalysts from liquid media is very difficult. To overcome this problem, one attractive route is their immobilization in solid hosts. Metal–organic frameworks (MOFs) have appeared as promising hosts, where catalytic centres can be encapsulated or moreover be part of the constituents of the materials. After pioneering work by Suslick and co-workers, a number of porphyrin-based MOFs have been reported, including some with photocatalytic properties.
Energy A New Way of Looking at Solar Cells Richard Martin; MIT Technology Review; 8 Jul 2016
- Perovskite crystals could be engineered to far outperform silicon.
- Thin film record 22.1 percent research cell continues performance advancement trend
AFRICA'S LARGEST SOLAR POWER PLANT TO BE SWITCHED ON TODAY Siyabonga Sesant; EyeWitness News (ZA); 17 Mar 2016
- The facility will produce power that's equivalent to providing electricity to about 75,000 homes a year.
- The facility which is based in De Aar, is expected to produce more than 175 megawatts of power.
- expected PV capacity factor for stations at De Aar is around 20-25% so 175MW / 75,000 * 0.25 = .58 kW / home max
- Power utility Eskom has also built a substation on the premises which will help store the electricity.
World's biggest floating solar farm powers up outside London Fiona Harvey; Guardian; 29 Feb 2016
- On a vast manmade lake on the outskirts of London, work is nearing completion on what will soon be Europe’s largest floating solar power farm – and will briefly be the world’s biggest. But few are likely to see the 23,000 solar panels on the Queen Elizabeth II reservoir at Walton-on-Thames, which is invisible to all but Heathrow passengers and a few flats in neighbouring estates. “This will be the biggest floating solar farm in the world for a time - others are under construction,” said Angus Berry, energy manager for Thames Water, which owns the site. “We are leading the way, but we hope that others will follow, in the UK and abroad.”
Floating Solar Power Plants To Become A Reality Michael Lazar Contributor, NowItCounts.com; Huffpo blogs; 1 May 2016
- In the not so distant future, the power we need could very well be provided by floating solar power plants that are offshore. Wind farms have become very popular in recent years and now experts are looking at ways to create sustainable energy without having to develop land. The solution: use the sea to house these structures. The Vienna University of Technology is currently working on such a technology. They are calling it the Heliofloat. It consists of a seafaring solar power station that has an open bottom and is flexible, about the size of a football field. Interestingly, they are designing them so that multiple platforms can conjoin to create a solar power grid, if need be. Rugged in their design, the floats will not capsize even in severe weather. Constructed using barrels to stay afloat with an open bottom that traps air, the floatables also prevent capsizing during even the worst of storms. There’s no word yet on when these new contraptions will be able to power our homes and businesses, but it’s a pretty innovative and cool idea nonetheless.
- StratoSolar PV power plants are constructed from buoyant, rigid, platforms that support large arrays of photovoltaic (PV) panels on their top surface. They float stationary in the low stratosphere at 20 kilometer (km) altitude (65,616 feet) for the thirty year life of the power plants. They are connected to the ground and held in place with strong and light Kevlar or UHMPE tethers. The tethers also support High Voltage (HV) power lines that transfer the electric power generated by the PV panels to the ground. Excess buoyancy in the floating platforms pre-tension the tethers and allow the platform to resist wind forces with small horizontal deflections. The pictures below show the size of a range of power plants from 5 Mega Watts rated power (MWp) to 10.3 Giga Watts rated power (GWp ).
- They propose tackling the problem of intermittency with storage via weights winched up to the floating platform
Concentrated Solar Power Wikipedia
Solar Heat Challenges Photovoltaics as Power Source Umair Irfan, ClimateWire; Scientific American; 14 Jan 2013
- Concentrated solar power may surpass photovoltaics as the solar technology of choice because the sun's heat is more easily stored
- In the United States, concentrated solar power (CSP) manifested in the 1980s as nine power plants in Southern California using trough-shaped mirrors to concentrate energy on a circulating heat transfer fluid. The fluid, often a synthetic oil, then heats up a molten salt to as high as 350 degrees Celsius, which then boils water to drive a turbine.
New Concentrating Solar Tower Is Worth Its Salt with 24/7 Power Knvul Sheikh; Scientific American; 14 Jul 2016
- A California firm is converting sunlight to heat and storing it in molten salt so it can supply electricity when the wind is calm or the sun isn’t shining
- Deep in the Nevada desert, halfway between Las Vegas and Reno, a lone white tower stands 195 meters tall, gleaming like a beacon. It is surrounded by more than 10,000 billboard-size mirrors focusing the sun’s rays on its tip
- The facility is touted as being the first solar power plant that can store more than 10 hours of electricity, which translates into 1,100 megawatt-hours, enough to power 75,000 homes
- Although a few other plants like the Solana Generating Station in Arizona have used molten salt as a storage medium, they heat the salt indirectly, using solar energy to first heat other fluids such as oil.
- when the cost of even the best battery technology is taken into consideration, photovoltaics are more expensive than concentrating solar power, which is now down to 10 to 12 cents per kilowatt-hour.
- Crescent Dunes is already nearly six times bigger than Torresol Energy’s 20 megawatt demonstration scale plant that was completed in 2011 in Spain. And SolarReserve is planning to break ground on a second plant roughly the same size as Crescent Dunes in South Africa later this year.
New Solar Energy Harnessing-Tech Even Works at Night Ramon Perez; Futurism; 9 Aug 2016
- Found in the middle of the dust and rocks of the Nevada desert, not to mention the blazing Sun above, Crescent Dunes‘ solar oasis can be found.
- Composed of a tall central tower surrounded by a total of 10,437 glass panels, with more than one million square meters (~10.8 million square feet) of glass, this solar oasis is capable of storing energy, enough to supply electricity to 75000 households during peak demand periods, 24/7.
- The central tower then secretes a reservoir of potassium and sodium nitrate—about 25,000 metric tonnes (~28,000 US tons) of it—heated in advance to 288°C (550°F), at which temperature the mixture is a clear, water-like liquid.
- This is then circulated in narrow, thin-walled tubes, rising dramatically in temperature when exposed to the fearsome, concentrated sunlight at the top of the tower. “We heat it to 560°C (1040°F),” says Smith, “it flows back down the tower and we capture it in a large tank.”
Ivanpah Solar Plant May Be Forced to Shut Down CASSANDRA SWEET; WSJ; 16 Mar 2016
- Federally backed project asks California regulators for more time to sort out its problems
Could California’s massive Ivanpah solar power plant be forced to go dark? MarketWatch (via Wall St Journal) 16 Mar 2016
- $2.2 billion desert project not generating enough energy; backers ask for more time
CPUC Gets It Right: PG&E Can Keep Its Ivanpah Contract Clean Technica; 18 Mar 2016
- The California Public Utilities Commission (CPUC) has approved PG&E’s December 18 request for a Forbearance Agreement for Ivanpah Units 1 and 3, giving the two units at least six months, and possibly a year, to meet current production targets of 448,000 MWh annually.
World's Largest Solar Project Would Generate Electricity 24 Hours a Day, Power 1 Million U.S. Homes Lorraine Chow; EcoWatch; 12 Oct 2016
- SolarReserve CEO Kevin Smith told the Las Vegas Review-Journal that the $5 billion endeavor would generate between 1,500 and 2,000 megawatts of power, enough to power about 1 million homes. That amount of power is as much as a nuclear power plant, or the 2,000-megawatt Hoover Dam and far bigger than any other existing solar facility on Earth, the Review-Journal pointed out.
Developer of huge solar array near Tonopah wants to build 10 more HENRY BREAN; LAS VEGAS REVIEW-JOURNAL; 11 Oct 2016
- A California-based energy company announced plans Tuesday to build the world’s largest solar project in Nevada, a $5 billion endeavor involving at least 100,000 mirrors and 10 towers as tall as any building in the state.
- SolarReserve’s Sandstone project would include up to 10 concentrated solar arrays, each equipped with a molten salt system capable of storing the sun’s energy to generate power after dark, CEO Kevin Smith said.
- The company already has built one such array, the 110-megawatt Crescent Dunes Solar Energy Plant, on 1,600 acres of federal land outside of Tonopah, 225 miles northwest of Las Vegas. The $1 billion array began delivering power to NV Energy late last year.
- Smith said project Sandstone would generate between 1,500 and 2,000 megawatts, enough to supply about a million homes. That’s on par with a nuclear power plant or the Hoover Dam and far bigger than any of the world’s existing solar facilities.
A review of concentrated solar power (CSP) in Spain Roger Andrews; Energy Matters; 2 Dec 2015
- Euan Mearn’s recent Red Eléctrica de España (REE) post drew my attention to the fact that REE has now begun to show grid data for solar PV and concentrated solar power (CSP) generation separately instead of lumping them together. In this post I use the REE data to review the performance of Spain’s CSP plants and to check among other things whether the claim that they are capable of providing baseload generation, as this 2011 Forbes article claimed, holds up in the light of operating experience. Spain is a good case study because the lion’s share of world CSP capacity (2.3 of 3.4GW in 2013) is installed there.
- Heat of up to 900C is used to warm molten salt tanks, which create steam to power the £260million station's turbines. But, unlike all other solar power stations, the heat stored in these tanks can be released for up to 15 hours overnight, or during periods without sunlight. The regular sunshine in southern Spain means the facility can therefore operate through most nights, guaranteeing electrical production for a minimum of 270 days per year, up to three times more than other renewable energies. The project, a joint venture between Abu Dhabu energy company Masdar and Spanish engineering firm SENER called Torresol Energy, took two years to construct at a cost of £260million. It is expected to produce 110 GWh/year - enough to power 25,000 homes in the Andalucia region.
bird etc casualties
One Weird Trick Prevents Bird Deaths At Solar Towers Susan Kraemer; CleanTechnica; 16 Apr 2015
- America’s second solar power tower, the 110 MW Crescent Dunes project, the first US power tower to include storage, has been undergoing final commissioning (testing) at Tonopah in Nevada, where it will supply power for Las Vegas till midnight.
- So SolarReserve is putting the thousands of heliostats (mirrors) through their paces to make sure everything works.
- One of the tests is of standby position. (Standby is when the heliostats are waiting to go to work making electricity by focusing on the tower receiver. During standby they are not aimed at the tower receiver, but somewhere in the air.)
- Originally, the standby position was to create a tight circle of solar flux you can actually see above the tower.
- But when the engineers focused 3,000 heliostats there on January 14th, 115 birds were killed as they flew through the concentrated solar flux at the focal point where all the reflections met.
- “So what we did is we spread them over a several hundred meters of a sort of ‘pancake’ shape so any one point is safe for birds — it’s 4 suns or less.”
- “We have had zero bird fatalities since we implemented this solution in January, despite being in the standby position as well as flux on the receiver for most days since then,” he said. “This change appears to have fully corrected the problem.”
molten silicon storage
Molten silicon offers tenfold improvement to solar energy storage Tereza Pultarova; Engineering & Technology; 7 Oct 2016
- According to the team from the Solar Energy Institute of the Universidad Politécnica de Madrid (UPM), up to 1MWh of energy can be stored in just one cubic metre of molten silicon. Combined with the fact that silicon is the most abundant element in the Earth’s crust, the technology holds a promise for solving the problem of intermittency of renewable power generation. The system, described in an article in the Energy journal, stores energy from solar rays at very high temperatures of up to 1400°C. The energy can be recovered when needed through a thermal generator. “At such high temperatures, silicon intensely shines in the same way that the sun does; thus photovoltaic cells, thermophotovoltaic cells in this case, can be used to convert this incandescent radiation into electricity,” explained Alejandro Datas, who led the research. “The use of thermophotovoltaic cells is key in this system, since any other type of generator would hardly work at extreme temperatures.” With conversion efficiency of up to 50 per cent, these thermophotovoltaic cells can produce 100 times more electric power per unit area than conventional solar cells. The technology is quite similar to the existing concepts of storing solar power in molten salts. However, the salts are not only ten times less efficient, they are also more expensive and harder to obtain. The team is currently awaiting a US patent and has started building a laboratory scale prototype that would pave the way for a commercial product. In addition to thermal solar power plants, the researchers envisage that the system could be used in the housing sector to provide electricity and heating to residential and office buildings.
solar wind energy
Solar Wind Energy Tower Inc company website
- claims "4380000 MWH annual production" so average 500MW
Half Mile High Tower in the Desert Could Generate as Much Power as the Hoover Dam Nidhi Goyal; Industry Tap; 5 Jul 2014
- half a mile (0.8 kilometres or 2,250 feet)
- "this tower can generate 1,250 megawatt-hours"
- (Presently, Hoover Dam can produce over 2,000 megawatts of capacity and a yearly average generation of 4.5 billion kilowatt hours )
Solar Wind Energy Tower Demonstration CleanWindEnergy; YouTube; 26 Mar 2013
- The following video demonstration displays the operation of the Downdraft Tower Technology.
- good brief explanation
Energy Towers Power & Water - Introductory Overview.mpg privatelands; YouTube; 18 Feb 2010
- A 5-minute 40-second overview of the Energy Towers technology. Developed at the Technion-Israel Institute of Technology by Prof. Dan Zaslavsky, this is the most cost-effective technology for supplying zero-emission electricity from renewable sources. Electricity can be produced more cheaply than with virtually any other technology, including wind turbine, solar, coal, natural gas and nuclear. There also are 13 beneficial byproducts, including the ability to cheaply desalinate sea water in huge volumes.
- Israeli - 1200m hight 400m diameter
Solar Updraft Tower MaoClausewitz ; YouTube; 11 Dec 2011
Solar Tower Energy Käyttäjän djpole76 kanava; YouTube; 13 Dec 2006
- This is the future project in Australia. It will be ready in 2012.
- 1000m high 200MW
Why Design Now?: Hope Solar Tower Cooper Hewitt; 5 May 2010
- Why? Solar towers capture solar energy to heat air under an expansive collector zone. Based on the principle that heat rises, this air flows towards the center of the collector through electricity-generating turbines and up and out of the tower, like a chimney. When built, the tower will be about 750 meters high and could produce enough electricity to power approximately 500 households.
- The sun's radiation is used to heat a large body of air under an expansive collector zone, which is then forced by the laws of physics (hot air rises) to move as a hot wind through large turbines to generate electricity.
- A single power station development will have the capacity to supply renewable energy to more than 100,000 typical American households or remove the equivalent of 220,000 typical motor vehicles from the roads.
Spain Solar Tower Energy in Spain, Madrid Käyttäjän djpole76 kanava; YouTube;
- collector 4.4Ha polyvinyl fluoride 0.1mm thick expect life 10-12 years around base, condensation at night 200m high 10m dia, 60kW max / 30kW ave, US$1M